[10], Cyclohexanone can be prepared from cyclohexanol by oxidation with chromium trioxide (Jones oxidation). ORL-RAT LD50 1620 mg kg-1, IPR-MUS LD50 1350 mg kg-1, SKN-RBT LD50 1000 mg kg-1, DANGER: FLAMMABLE, causes CNS injury, lung & eye irritation, P210-P261-P280-P303+P361+P353-P403+P235-P501a, S9,S16,S23,S24/25,S26,S33,S36/37/39,S38,S45, Eye: Irrigate immediately Skin: Water flush promptly Breathing: Respiratory support Swallow: Medical attention immediately, inhalation, skin absorption, ingestion, skin and/or eye contact, Irritation eyes, skin, mucous membrane; headache; narcosis, coma; dermatitis; in animals: liver, kidney damage, Eyes, skin, respiratory system, central nervous system, liver, kidneys, Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: No recommendation, NIOSH REL : TWA 25 ppm (100 mg/m 3 ) [skin] OSHA PEL ? By now, I am beginning to wish I had followed the example of Kemp, W. Qualitative Organic Analysis (2nd Edn.). I hope this goes some way to answering your question! London:Harrap. Cyclohexanone is slightly soluble in water and miscible with common organic solvents. Control (Chinese), 14(5), 1992, 35-38. umn class: Standard non-polar; Column diameter: 0.50 mm; Column length: 23 m; Column type: Capillary; Start T: 110 C; CAS no: 108941; Active phase: OV-101; Data type: Normal alkane RI; Authors: Wang, H.; Deng, Z.; Song, L.; Jiang, W., Analysis of volatile organic pollutants with Curie point desorption gas chromatographic method. ; Peng, C.T., Structure assignment by retention index in gas-liquid radiochromatography of substituted cyclohexenes, J. ; Ma, W.C.J. 2. Articles of Cyclohexanone are included as well. (Engl. Physchim62 19:33, 25 August 2005 (UTC), Don't worry, as a professional chemist the Aldrich catalogue is my single most used source for physical data on compounds (it's free, there's always a copy lying around whichever lab I'm working in). Bull. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Particle size distribution (Granulometry), Solubility in organic solvents / fat solubility, Stability in organic solvents and identity of relevant degradation products, Storage stability and reactivity towards container material, Biodegradation in water and sediment: simulation tests, Additional information on environmental fate and behaviour, Short-term toxicity to aquatic invertebrates, Long-term toxicity to aquatic invertebrates, Toxicity to aquatic algae and cyanobacteria, Toxicity to aquatic plants other than algae, Endocrine disrupter testing in aquatic vertebrates – in vivo, Toxicity to soil macroorganisms except arthropods, Endocrine disrupter mammalian screening – in vivo (level 3), Direct observations: clinical cases, poisoning incidents and other, Exposure related observations in humans: other data, Additional physico-chemical properties of nanomaterials, Toxicokinetics, metabolism and distribution. Pollut. Food Chem., 54, 2006, 5087-5091. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(5min) =>4C/min => 230C(20min)=> 5C/min => 280C (5min); CAS no: 108941; Active phase: SE-54; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Gao, H.; Zhao, T.; Kong, Q.; Chen, X.; Hu, Z., Analysis of unknown organic pollutants in sewage by solid-phase extraction combined with gas chromatography-mass spectrometry, J. Chromatogr. Michael T. Musser "Cyclohexanol and Cyclohexanone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. Experimental Boiling Point: 113-116 deg C / 20 mm (244.8828-248.8132 °C / 760 mmHg) Alfa Aesar 113-116 °C / 20 mm (244.8828-248.8132 °C / 760 mmHg) Alfa Aesar A15612 If you have any questions, or need the bot to ignore the links, or the page altogether, please visit this simple FaQ for additional information. A discrepancy of this size can only really be due to supercooling, which would also mean that the higher values represent the "true" melting point. Chem. National Institute for Occupational Safety and Health, Data extract from Landolt-Börnstein IV/25: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures, "Phenol -- The essential chemical industry online", https://en.wikipedia.org/w/index.php?title=Cyclohexanone&oldid=974312047, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 22 August 2020, at 08:07. Cyclohexanone oxime was examined for mutagenic activity in Salmonella typhimurium tester strains TA98, TA100, TA1535, TA1537 and TA1538 in the presence and absence of metabolic activation provided by rat liver S9 fraction. Handbook of Chemistry and Physics (53rd Edn.). 2005-03-26 . Am. London:McGraw-Hill. : TWA 50 ppm (200 mg/m 3 ). Control (Chinese), 14(5), 1992, 35-38. class: Standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Description: 50C(8min) =>3C/min =>150C =>35C/min =>275C (10min); CAS no: 108941; Active phase: SE-30; Carrier gas: N2; Data type: Normal alkane RI; Authors: Ibrahim, E.A. A, 1216, 2009, 1630-1639. umn class: Standard non-polar; Column type: Capillary; Start T: 100 C; CAS no: 108941; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Lebron-Aguilar, R.; Quintanilla-Lopez, J.E. ; Pereira, W.E., Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest, J. Hi. Product Classification | The reference for this last value appears to be Sellers, P.; & Sunner, S. (1962). A resorcinol-formaldehyde-based organic aerogel is used... Metabolic activation of chemicals (prohaptens) in the skin can cause allergic contact dermatitis. ; Khanuja, S.P.S., Essential oil composition of Cymbopogon martinii from different places in India, Flavour Fragr. Oxidative effects in human erythrocytes caused by some oximes and hydroxylamine. This information has not been reviewed or verified by the Agency or any other authority. Food Sci., 53(6), 1988, 1666-1670. ass: Standard polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 65 C; End T: 250 C; End time: 60 min; Start time: 10 min; CAS no: 108941; Active phase: AT-Wax; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Pino, J.A. Quantitative analysis., Environ. Chem., 21, 1968, 1125-1141. ass: Standard polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 200 C; Start time: 5 min; CAS no: 108941; Active phase: CBP-20; Carrier gas: He; Phase thickness: 0.25 um; Data type: Kovats RI; Authors: Shimadzu, Gas chromatography analysis of organic solvents using capillary columns (No. Stable. Biologically Active Compounds | Combustible. The perfumers' references also recommend you smell it in 1% or less concentration. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. Chem. ; Ding, S.F. ; Anvaer, B.I. .CS1 maint: extra punctuation (link), all of whom decline to give a value for the melting point! Articles of Cyclohexanone oxime are included as well. Food Sci. Journals | ; Ramsey, J.D., Volatile Substance Abuse, UNODC Technical Series, No 5, United Nations, Office on Drugs and Crime, Vienna International Centre, PO Box 500, A-1400 Vienna, Austria, 1997, 56. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 108941; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. "Heats of combustion of cyclic ketones and alcohols". A, 963, 2002, 381-392. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 10 min; Start time: 0.5 min; CAS no: 108941; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Guillen, M.D. Cyclohexanone oxime CAS Number 100-64-1 Molecular Weight 113.158 Density 1.1±0.1 g/cm3 Boiling Point 208.0±0.0 C at 760 mmHg Molecular Formula C 6 H 11 NO Melting Point 86-89 C(lit.) ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Alternatively, cyclohexanone can be produced by the partial hydrogenation of phenol: This process can also be adjusted to favor the formation of cyclohexanol. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Quantitative analysis., Environ. Food Chem., 47, 1999, 5151-5160. ass: Standard polar; Column diameter: 0.32 mm; Column length: 50 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 60 C; End T: 220 C; End time: 30 min; Start time: 5 min; CAS no: 108941; Active phase: CP-Wax 52CB; Data type: Linear RI; Authors: Chevance, F.F.V. A, 1160, 2007, 276-288. umn class: Standard non-polar; Column type: Capillary; Start T: 140 C; CAS no: 108941; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Lebron-Aguilar, R.; Quintanilla-Lopez, J.E.

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